If you have a powerful enough PC (Core i5 3+Ghz upwards), you could also emulate Wii and Gamecube games. That's what I'm currently doing. A bit wonky sometimes, but at least you get high resolutions out there.
Either way, excellent choice. Metroid Prime trilogy, Donkey Kong Returns, Metroid Other M, The Last Story and Zelda feel very refreshing to me. However you should think about getting the Premium Pack with 32 GB instead, unless you intend to plug in an external HDD.