edit: damn but the UI art(texture) looks so much better then the one in PoE.
Actually no it really doesn't. It is blatantly low res and looks pixelated.
That said this is easy to do with custom portraits. You just start with a very large image, make the "large pic" a full body shot, then make the "small pic" just a focus on the head and shoulders. Here is a concept image I just tossed together to show what I mean. Original image I used in the top right, and the portrait and status screens are pasted in as well.